Washable thermoplastic elastomer foam and articles incorporating same

ABSTRACT

A thermoplastic elastomer (TPE) foam having a soft open-cell inner layer and a washable closed-cell outer layer which surrounds and substantially seals the inner layer, and which may be used alone or in combination with other components to produce useful articles. The TPE foam includes a base resin which is a styrenic block copolymer, and a foaming agent. A process of forming and molding the TPE foam includes using a shutoff nozzle to prevent the foaming agent from activating before reaching the mold cavity, using an oversized gate to minimize shear heat, and using oversized vents. An earplug may be constructed by molding the TPE foam over a core or body formed from a material which is denser than the TPE foam. A first earplug design may employ a constrained layer damping effect, while a second earplug design may employ an adjustable sound attenuation effect.

FIELD

The present invention relates to foams and articles incorporating foams,and more particularly to a thermoplastic elastomer foam having anopen-cell inner layer and a washable closed-cell outer layer whichsurrounds and substantially seals the open-cell inner layer, andarticles incorporating the washable thermoplastic elastomer foam.

BACKGROUND

So-called “foam earplugs” are often used to attenuate sound. Foamearplugs are typically constructed of either polyvinyl chloride (PVC) orpolyurethane (PU) (so-called “memory foam”) material which can becompressed and positioned in the user's ear where it expands to fill theear. Foam earplugs suffer from several disadvantages. In particular, theopen-cell structure accumulates dirt and cannot be effectively washed.The open cell structure also accumulates ear wax and oil and can harborbacteria. As a result, foam earplugs are generally only worn once andthen discarded. Further, producing and using products constructed of PVCand PU materials can involve exposure to highly toxic chemicals whichcan be hazardous to people and the environment. For example, PVC is madefrom petroleum and may include phthalates, and the production processuses sodium chloride, and PU may include isocyanates, amine catalysts,polyols, and flame retardants.

This background discussion is intended to provide information related tothe present invention which is not necessarily prior art.

SUMMARY

Embodiments of the present invention solve the above-described and otherproblems and limitations by providing a thermoplastic elastomer (TPE)foam having a soft open-cell inner layer and a washable closed-cellouter layer which surrounds and substantially seals the open-cell innerlayer, and which may be used alone or in combination with othercomponents to produce useful articles, such as earplugs. In contrast toprior art foams, the TPE foam is less toxic to produce and articlesincorporating the TPE foam can be washed and reused.

In a first embodiment, a TPE foam body may comprise an open-cell innerlayer and a closed-cell outer layer. The inner and outer layers may beformed from an identical base resin which includes a styrenic blockcopolymer. The closed-cell outer layer may surround and substantiallyseal the open-cell inner layer.

Various implementations of the first embodiment may include any one ormore of the following additional features. The TPE foam may have a Shorehardness value of approximately between OO 15 and OO 40. The closed-cellouter layer may be approximately between 0.015 inches and 0.020 inchesthick. The TPE body may be molded in the form of an earplug adapted tobe inserted and retained in an ear of a user.

In a second embodiment, an article may comprise a core and a TPE foam.The core may be constructed of a core material and include a centralbody having a longitudinal axis. The TPE foam may be molded over atleast a portion of the core and have an open-cell inner layer and aclosed-cell outer layer. The inner and outer layers may be formed froman identical base resin which includes a styrenic block copolymer. Theclosed-cell outer layer may surround and substantially seal theopen-cell inner layer. The core material may have a higher density thanthe TPE foam.

Various implementations of the second embodiment may include any one ormore of the following additional features. The core material may beconstructed of a mixture containing a base substrate and one or moreminerals of approximately between 30% and 40% total weight. The centralbody may have a Shore hardness value of at least A 40-80. An end of thecentral body may include a button structure configured to aid insertionof the article into a cavity, such as an ear of a user. The TPE foam mayhave a Shore hardness value of approximately between OO 15 and OO 40.The closed-cell outer layer may be approximately between 0.015 inchesand 0.020 inches thick. The core may further include one or more finsarranged in a longitudinally spaced apart relationship along at least aportion of the central body and extending radially outward from thelongitudinal axis of the central body. The fin structures may each havea thickness of approximately between 0.012 inches and 0.024 inches.

In a third embodiment, an article may comprise a body, a valve assembly,and a TPE foam material. The body may be constructed from a bodymaterial and include a longitudinal tunnel arranged along a longitudinalaxis. The valve assembly may be constructed of a valve assembly materialand coupled with the body, and include a disk defining at least oneshield and at least one hole, and a knob defining at least one inlet.The knob may be repositionable relative to the disk so as to increase analignment of the inlet with the shield and thereby decrease an amount ofsound entering the longitudinal tunnel, and to increase an alignment ofthe inlet with the hole and thereby increase the amount of soundentering the longitudinal tunnel. The TPE foam may be molded over atleast a portion of the body and have an open-cell inner layer and aclosed-cell outer layer. The inner and outer layers may be formed froman identical base resin which includes a styrenic block copolymer. Theclosed-cell outer layer may surround and substantially seal theopen-cell inner layer. The body material may have a higher density thanthe TPE foam.

Various implementations of the third embodiment may include any one ormore of the following additional features. The body material may beconstructed of a mixture containing a base substrate and one or moreminerals of approximately between 30% and 40% total weight. The body mayhave a Shore hardness value of at least A 40-80. The valve assemblymaterial may be harder than the body material. The knob may furtherinclude a head to facilitate grasping and repositioning the knobrelative to the disk. The TPE foam may have a Shore hardness value ofapproximately between OO 15 and OO 40. The closed-cell outer layer maybe approximately between 0.015 inches and 0.020 inches thick. The TPEmaterial may be further molded, inserted, or otherwise provided betweenthe disk and the knob so as to increase a seal between the disk and theknob, and/or the TPE material may be further molded, inserted, orotherwise provided between the disk and the body so as to increase aseal between the disk and the body.

In a fourth embodiment, a method of forming a TPE foam body by injectionmolding of a TPE base resin into a vented mold cavity may comprise thefollowing. The TPE base resin may be mixed with a foaming agent tocreate a mixture. The TPE base resin may include a styrenic blockcopolymer having a processing profile, and the foaming agent may beapproximately between 1% and 4% by total weight and may have anactivation temperature that is compatible with the processing profile ofthe base resin. The mixture may be maintained at approximately between240 degrees F. and 320 degrees F. A shutoff nozzle may be used to createa backpressure within the mixture of approximately between 1000 psi and3000 psi so as to prevent the foaming agent from activating beforeinjection into the mold cavity. At least one gate may be used which isoversized in order to minimize a shear heat at an injection speed atwhich the mixture is injected through the gate. The mold cavity may beheated to approximately between 100 degrees F. and 140 degrees F. toform the closed-cell outer layer having a thickness of approximatelybetween 0.015 inches and 0.020 inches. The vented mold cavity having atleast one vent that is sized to rapidly vent the mold cavity and tofacilitate unconstrained foam cell growth within the mold cavity therebyforming the thermoplastic elastomer foam body comprising an open-cellinner layer and a closed-cell outer layer which surrounds andsubstantially seals the open-cell inner layer.

Various implementations of the fourth embodiment may include any one ormore of the following additional features. The TPE foam body may have aShore hardness value of approximately between OO 15 and OO 40. Themethod may further include mixing a nucleating agent into the mixture,and the nucleating agent may be talc or gypsum. The method may furtherinclude using an injection accumulator cylinder to increase theinjection speed of the mixture through the at least one gate.

This summary is not intended to identify essential features of thepresent invention, and is not intended to be used to limit the scope ofthe claims. These and other aspects of the present invention aredescribed below in greater detail.

DRAWINGS

Embodiments of the present invention are described in detail below withreference to the attached drawing figures, wherein:

FIG. 1 is a fragmentary cross-sectional view of an embodiment of a TPEfoam of the present invention;

FIG. 2 is a flowchart of an embodiment of a process of forming andmolding the TPE foam of FIG. 1;

FIG. 3 is a cross-sectional elevation view of a first embodiment of aconstrained layer damping earplug article constructed using the TPE foamof FIG. 1;

FIG. 4 is a cross-sectional elevation view of a second embodiment of theconstrained layer damping earplug article constructed using the TPE foamof FIG. 1;

FIG. 5 is a fragmentary cross-sectional elevation view of the earplugarticle of FIG. 4; and

FIG. 6 is an exploded isometric view of an embodiment of a soundattenuation earplug article constructed using the TPE foam of FIG. 1.

The figures are not intended to limit the present invention to thespecific embodiments they depict. The drawings are not necessarily toscale.

DETAILED DESCRIPTION

The following detailed description of embodiments of the inventionreferences the accompanying figures. The embodiments are intended todescribe aspects of the invention in sufficient detail to enable thosewith ordinary skill in the art to practice the invention. Otherembodiments may be utilized and changes may be made without departingfrom the scope of the claims. The following description is, therefore,not limiting. The scope of the present invention is defined only by theappended claims, along with the full scope of equivalents to which suchclaims are entitled.

In this description, references to “one embodiment”, “an embodiment”, or“embodiments” mean that the feature or features referred to are includedin at least one embodiment of the invention. Separate references to “oneembodiment”, “an embodiment”, or “embodiments” in this description donot necessarily refer to the same embodiment and are not mutuallyexclusive unless so stated. Specifically, a feature, structure, act,etc. described in one embodiment may also be included in otherembodiments, but is not necessarily included. Thus, particularimplementations of the present invention can include a variety ofcombinations and/or integrations of the embodiments described herein.

Broadly characterized, referring to FIG. 1, embodiments of the presentinvention provide a thermoplastic elastomer (TPE) foam 10 having a softopen-cell inner layer 12 and a washable closed-cell outer layer 14 whichsurrounds and substantially seals the open-cell inner layer 12 at leastfrom an external environment. More specifically, during formation of theTPE foam 10 in a vented mold cavity, the closed-cell outer layer 14forms over the open-cell inner layer 12 to surround and substantiallyseal the open-cell inner layer 12 so that dirt or other undesirablematerial does not reach or accumulate in or on the open-cell inner layer12 and can be effectively washed off of the closed-cell outer layer 14.As used herein, the phrase “substantially seals” may mean makingimpervious to the passage of water and/or dirt or other undesirablematerial or making resistant to the passage of water and/or dirt orother undesirable material. The TPE foam 10 may be used alone or incombination with other components to produce useful articles, such asearplugs. In contrast to prior art foams, the TPE foam 10 is less toxicto produce and articles incorporating the TPE foam 10 can be washed andreused.

Embodiments of the TPE foam 10 may be formed from a composition broadlycomprising a base resin and a foaming agent. The base resin may besubstantially any suitable styrenic block copolymer having a processingprofile including a processing temperature. For at least someapplications (e.g., earplugs), it may be desirable that the TPE materialhave a Shore hardness value of approximately between OO 15 and OO 40,and high elastomeric and flexural modulus properties. For at least someapplications involving contact with skin, a TPE material approved by theU.S. Food and Drug Administration may be appropriate. Exemplary styrenicblock copolymer TPE materials include styrene-butadiene-styrene (SBS)block copolymers, styrene-isoprene-styrene (SIS) block copolymers, andhydrogenated styrenic block copolymers (HSBC).

For at least some applications in which the TPE foam 10 is to beovermolded onto a substrate (examples of which are described below), itmay be desirable that the base resins of both the TPE foam 10 and thesubstrate be molecularly compatible in order to chemically bond andadhere to each other when the TPE foam 10 is injected into the moldcavity at a desired processing temperature. In particular, if therequired TPE foam injection temperature is too hot for adhesion with thesubstrate, then activation of the TPE foam 10 may be extreme andinconsistent, and blisters and large bubbles may occur. Low glasstransition and melt temperatures for both the TPE foam 10 and thesubstrate may be desirable to allow for more controlled gassing andendothermic reaction prior to filling the mold cavity. The temperatureprofile may be a bell curve.

The foaming agent may be substantially any suitable foaming agent, suchas Actifoam®, Foamisol, or Fafoam. The foaming agent functions to reduceresin volume by releasing a gas which creates air voids in the baseresin, thereby lowering overall material costs. The foaming gases may becreated by endothermic decomposition. Maximum gas yields may be achievedwhen processing temperatures of approximately between 374 degrees F. and437 degrees F. are reached. For some applications, the foaming agent maybe provided in a powder media form in order to facilitate mixing withthe base resin and achieving a mixed homogenous ratio blend. To achieveproper ratios, an amount of foaming agent of approximately between 1%and 4% total weight may be used. The activation temperature of thefoaming agent should be compatible with the processing profile of thebase resin.

For at least some applications, it may be desirable to add a nucleatingagent, such as talc or gypsum, to create a more consistent andhomogenous foam body throughout the article.

For at least some articles (e.g., earplugs) into which the TPE foam 10may be incorporated, the washable closed-cell outer layer 14, or “skin”,may be approximately between 0.015 inches and 0.020 inches thick. Asdiscussed below in more detail, an elevated mold temperature may be usedto achieve a desired thickness.

Broadly characterized, referring to FIG. 2, an embodiment of a processof making and molding the TPE foam 10 may proceed substantially asfollows. The base resin, foaming agent, and any other components of thecomposition (e.g., a nucleating agent) may be mixed, as shown in 110, toform a substantially homogenous mixture in order to create consistentand cohesive dispersement of the foam body and walls.

A temperature profile in the form of a bell curve approximately between240 degrees F. and 320 degrees F. may be maintained, as shown in 112, inorder to control the desired foaming action. Processing temperaturesthat are too high may create blisters, and uncontrolled endothermicreactions may create undesirable conditions within the processingequipment.

The injection unit (not shown) operable to introduce the resin mixtureinto the mold may be equipped with a shutoff nozzle operable to deliverapproximately between 1000 psi and 3000 psi of back pressure into theinjection unit barrel, as shown in 114, to prevent foam cell formationin the system before the mixture reaches the mold cavity. Pressure dropsprior to cavity fill may be minimized, and significant drops uponreaching the cavity, spurs, and/or runners may be kept short and sealedoff. After the injection cycle, no packing may be required with anunconstrained cavity fill.

At least one gate may be used which is approximately between two to fourtimes the gate size that might normally be used for this type ofinjection molding process, as shown in 116, in order to minimize shearheat at high injection speed. Further, an injection accumulator cylindermay be used, as shown in 118, to increase injection speed through thegate and reduce the time before the pressure drops.

To create the washable closed-cell outer layer 14, the mold cavity maybe heated to approximately between 100 degrees F. and 140 degrees F., asshown in 120, depending on such factors as the foaming agent, the moldmaterial, and the cavity volume and shape. Higher cavity temperaturesmay result in a thicker outer layer 14, so the cavity temperature may bechosen to balance the thickness of the outer layer 14 with the thicknessof the inner layer 12 to achieve a desired overall result.

At least one vent may be used which is approximately between fifteen andtwenty times the vent size which might normally be used for this type ofinjection molding process, as shown in 122, in order to minimizeconstraint and inhibition on endothermic cell formation and therebyfacilitate fully populating the mold cavity with the TPE foam material.Larger vents may allow the TPE foam material to enter the vents, and soit may be desirable to trim any excess material from the finishedarticle.

The TPE foam 10 having a washable closed-cell outer layer 14 may beemployed alone or in combination with other components to create usefularticles. Broadly characterized, referring to FIGS. 3 and 4, one suchuseful article may be an earplug 210 providing a constrained layerdamping effect. An embodiment of the earplug 210 may broadly include asound damping core component 212 over at least a portion of which theTPE foam 10 may be molded. The core component 212 may include a centralbody 214 having a longitudinal axis 216, and may further include one ormore fin structures 218 (seen in FIG. 4) arranged in a spaced apartrelation along at least a portion of the central body 214 and extendingradially (e.g., substantially perpendicularly) outward from thelongitudinal axis 216 of the central body 214.

The sound damping core material should be compatible with the TPE foammaterial to facilitate the overmolding process. The core material may beformed of a mixture including a base substrate and a sound dampingfiller. Substantially any suitable sound damping filler may be used,such as one or more minerals of approximately between 30% and 50% totalweight and blended substantially homogenously with the base substrate.

For at least some applications, the core material may have a Shorehardness value of approximately A 40-80 in order to facilitate properinsertion and comfort. In particular, the dense but flexible core mayact as a plunger for the earplug fitting process by providing sufficientrigidity to push the end covered by the TPE foam 10 into the ear.Relatedly, the opposite end of the central body 214 may present a buttonor other structure 220 to further facilitate pushing the earplug intothe ear.

The core material may have a higher density than the TPE foam 10 so thatonce the TPE foam 10 is molded over at least a portion of the corecomponent 212 that is insertable into the ear canal 220 (FIG. 5), thedifferent layers of materials having different densities may function todampen sound entering the ear. More specifically, the higher densityminerals or fillers and lower density inner and outer layers mayfunction to modify the path of sound propagation. As a result, theconstrained damping design may dissipate and reduce the amplitude ofsound waves through noise reflection (reflecting the sound waves off oneor more barriers), noise absorption (converting acoustic energy intoheat energy), and noise dissipation (distorting the sound waves throughmultiple layers). Referring to FIGS. 4 and 5, this effect may besignificantly enhanced by the addition of the one or more finsstructures 218 so that sound waves encounter multiple layers of thematerials having different densities. For at least some applications,the fin structures 218 may be approximately between 0.012 inches and0.024 inches in thickness. If the fin structures are too thin, they maynot provide a desired level of constrained layer damping, and if the finstructures are too thick, they may interfere with fit and comfort. Asshown in FIG. 5, in particular, the closed cell layer 14 also forms onthe interface between the open cell layer 12 and central body 214. Thus,sound waves traversing the central axial portion of the ear plug aredirected through numerous transitions between materials of differentdensity. For example, the sound wave may initially pass through closedcell layer 14 into open cell layer 12, through closed cell layer 14,through fin structure 218, through closed cell layer 14, through opencell layer 12, etc. As depicted in FIG. 5, soundwaves 222 impinging uponthe ear canal 220 are directed through ear plug 210. At least a portionof the soundwaves 224 that pass through portions of ear plug 210 aredeflected in response to passage through the varying components ofdiffering density that comprise the ear plug. This change in direction,indicated by arrows 226, results in sound being directed away from theinterior portion of ear canal 220, and thus away from the user's eardrum (not shown). In addition, at least a portion of the sound energytraveling through the various layers of differing density are dissipatedas heat, represented by arrows 227. The constrained layer damping effectproduced by ear plug 210 results in the transmission of soundwaves 228into the interior of ear canal 220 that are greatly reduced in intensityas compared to soundwaves 222.

Broadly characterized, referring to FIG. 6, another such useful articlemay be an earplug 310 providing an adjustable sound attenuation effect.Details of an exemplary sound attenuating earplug may be found in U.S.Pat. Nos. 8,820,470 and 9,278,031, the contents of both of which arehereby incorporated by reference into the present discussion in theirentireties. An embodiment of the earplug 310 may broadly include a body312 and a valve assembly 314 over at least a portion of which the TPEfoam 10 may be molded or otherwise applied.

The body 312 may have a generally elongated shape and define alongitudinal tunnel 316 arranged along a longitudinal axis 320. The body312 may be constructed of substantially any suitable material, such as apolymer material having a relatively soft Shore hardness value, such as,for example, ASTM D2240 type A polypropylene, or the same or similarmaterial as the earplug 210, described above, having a Shore hardnessvalue of approximately A 40-80 in order to facilitate proper insertionand comfort.

The valve assembly 314 may include a mated disk 326 and knob 328. Theknob 328 may be rotatable, slidable, or otherwise repositionablerelative to the disk 326 in order to adjustably attenuate sound. In oneimplementation, the knob 328 may include a split prong 340, and the disk326 may present a through-hole 342, and the knob 328 may be rotatablycoupled with the disk 326 by the split prong 340 extending through andengaging the through-hole 342. The valve assembly 314 may be constructedof a harder material than the body 312 so as to transfer the appliedforces and accomplish overall function of the earplug 310. As such, thevalve assembly 314 may be constructed of cellulose, metal, or polymerssuch as polypropylene, polyurethane, polyethylene, or blends thereof.The valve assembly 314 may be removably coupled to the body 312, so asto facilitate cleaning and maintenance of the ear plug 310.

The disk 326 may alternately define at least one shield 330 and at leastone hole 332, and more preferably, a plurality of shields 330 and holes332. The knob 328 may define at least one inlet 334, and morepreferably, first and second inlets 334, and may include a head 336configured to facilitate grasping and manipulating the knob 328. Theinlets 334 of the knob 328 operate in conjunction with the shields 330and the holes 332 of the disk 326, such that rotating the knob 328 toincrease the alignment of the inlets 334 and the shields 330 decreasesthe amount of sound entering the tunnel 316, and rotating the knob toincrease the alignment of the inlets 334 and the holes 332 increases theamount of sound entering the tunnel 316. Thus, in operation, a userwearing the earplug 310 may manually rotate the head 336 of the knob328, so as to gradually align the inlets 334 with the shields 330 or theholes 332 in order to respectively increase or decrease the soundattenuation effect.

The TPE foam 10 may be incorporated into the earplug 310 in at leasteither or both of two ways. First, the TPE foam 10 may be molded over atleast a portion of the body 312 that is insertable into the ear. Second,the TPE foam 10 may be molded, applied, or otherwise positioned as agasket or membrane 342 between the knob 328 and the disk 326 and/or as agasket or membrane 344 between the disk 326 and the body 312 in order toenhance the pneumatic and acoustic seals therebetween. In someapplications, the seal may be configured to slowly leak so as toequalize a pressure difference between the interior of the longitudinaltunnel 316 and the external environment, which may be advantageous incertain contexts, such as when traveling in an airplane.

In certain embodiments described herein, the ear plugs are capable ofachieving a noise reduction rating (NRR) of at least 30 dB, at least 33dB, or at least 34 dB.

Although the invention has been described with reference to the one ormore embodiments illustrated in the figures, it is understood thatequivalents may be employed and substitutions made herein withoutdeparting from the scope of the invention as recited in the claims.

Having thus described one or more embodiments of the invention, what isclaimed as new and desired to be protected by Letters Patent includesthe following:
 1. A thermoplastic elastomer foam body comprising anopen-cell inner layer and a closed-cell outer layer, both the open-cellinner layer and the closed-cell outer layer being formed from a baseresin which includes a styrenic block copolymer, and the closed-cellouter layer surrounding and substantially sealing the open-cell innerlayer.
 2. The thermoplastic elastomer foam body of claim 1, wherein thethermoplastic elastomer foam body has a Shore hardness value of betweenOO 15 and OO
 40. 3. The thermoplastic elastomer foam body of claim 1,wherein the closed-cell outer layer is between 0.015 inches and 0.020inches thick.
 4. The thermoplastic elastomer foam body of claim 1,wherein the thermoplastic elastomer foam body is molded in the form ofan earplug adapted to be inserted and retained in an ear of a user. 5.An article comprising: a core constructed of a core material andincluding a central body having a longitudinal axis; and a thermoplasticelastomer foam molded over at least a portion of the core and having anopen-cell inner layer and a closed-cell outer layer, both the open-cellinner layer and the closed-cell outer layer being formed from a baseresin which includes a styrenic block copolymer, and the closed-cellouter layer surrounding and substantially sealing the open-cell innerlayer, wherein the core material has a higher density than thethermoplastic elastomer foam.
 6. The article of claim 5, wherein thecore material is constructed of a mixture containing a base substrateand one or more minerals of between 30% and 40% total weight.
 7. Thearticle of claim 5, wherein the central body has a Shore hardness valueof at least A 40-80.
 8. The article of claim 5, wherein an end of thecentral body includes a button structure configured to aid insertion ofthe article into a cavity.
 9. The article of claim 5, wherein thethermoplastic elastomer foam has a Shore hardness value of between OO 15and OO
 40. 10. The article of claim 5, wherein the closed-cell outerlayer is between 0.015 inches and 0.020 inches thick.
 11. The article ofclaim 5, the core further including one or more fins arranged in alongitudinally spaced apart relationship along at least a portion of thecentral body and extending radially outward from the longitudinal axisof the central body.
 12. The article of claim 11, wherein the one ormore fin structures each have a thickness of between 0.012 inches and0.024 inches.
 13. The article of claim 5, wherein the article is in theform of an earplug adapted to be inserted and retained in an ear of auser.
 14. An article comprising: a body constructed from a body materialand including a longitudinal tunnel arranged along a longitudinal axis;a valve assembly constructed of a valve assembly material and coupledwith the body, and including— a disk defining at least one shield and atleast one hole, and a knob defining at least one inlet, with the knobbeing repositionable relative to the disk so as to increase an alignmentof the at least one inlet with the at least one shield and therebydecrease an amount of sound entering the longitudinal tunnel, and toincrease an alignment of the at least one inlet with the at least onehole and thereby increase the amount of sound entering the longitudinaltunnel; and a thermoplastic elastomer foam molded over at least aportion of the body and having an open-cell inner layer and aclosed-cell outer layer, both the open-cell inner layer and theclosed-cell outer layer being formed from a base resin which includes astyrenic block copolymer, and the closed-cell outer layer surroundingand substantially sealing the open-cell inner layer, wherein the bodymaterial has a higher density than the thermoplastic elastomer foam. 15.The article of claim 14, wherein the body material is constructed of amixture containing a base substrate and one or more minerals of between30% and 40% total weight.
 16. The article of claim 14, wherein the bodyhas a Shore hardness value of at least A 40-80.
 17. The article of claim14, wherein the valve assembly material is harder than the bodymaterial.
 18. The article of claim 14, the knob further including a headto facilitate grasping and repositioning the knob relative to the disk.19. The article of claim 14, wherein the thermoplastic elastomer foamhas a Shore hardness value of between OO 15 and OO
 40. 20. The articleof claim 14, wherein the closed-cell outer layer is between 0.015 inchesand 0.020 inches thick.
 21. The article of claim 14, wherein thethermoplastic elastomer material is further provided between the diskand the knob so as to increase a seal between the disk and the knob. 22.The article of claim 14, wherein the thermoplastic elastomer material isfurther provided between the disk and the body as a seal between thedisk and the body.
 23. A method of forming a thermoplastic elastomerfoam body by injection molding of a thermoplastic elastomer base resininto a vented mold cavity, the method comprising the steps of: mixingthe thermoplastic elastomer base resin and a foaming agent to create amixture, wherein the base resin includes a styrenic block copolymerhaving a processing profile, the foaming agent is between 1% and 4% bytotal weight, and the foaming agent having an activation temperaturewhich is compatible with the processing profile of the base resin;maintaining the mixture at between 240 degrees F. and 320 degrees F.;using a shutoff nozzle to create a backpressure within the mixture ofbetween 1000 psi and 3000 psi so as to prevent the foaming agent fromactivating before injection into the mold cavity; using at least onegate which is oversized in order to minimize a shear heat at aninjection speed at which the mixture is injected through the at leastone gate; and heating the mold cavity to between 100 degrees F. and 140degrees F. to form the closed-cell outer layer having a thickness ofbetween 0.015 inches and 0.020 inches; the vented mold cavity having atleast one vent that is sized to rapidly vent the mold cavity and tofacilitate unconstrained foam cell growth within the mold cavity therebyforming the thermoplastic elastomer foam body comprising an open-cellinner layer and a closed-cell outer layer which surrounds andsubstantially seals the open-cell inner layer.
 24. The method of claim23, wherein the thermoplastic elastomer foam body has a Shore hardnessvalue of between OO 15 and OO
 40. 25. The method of claim 23, furtherincluding mixing a nucleating agent into the mixture.
 26. The method ofclaim 25, wherein the nucleating agent is talc or gypsum.
 27. The methodof claim 23 further including using an injection accumulator cylinder toincrease the injection speed of the mixture through the at least onegate.